Manuscript_Kumric et al.pdf (367.11 kB)
Membrane-assisted liquid phase extraction of Lu(III) in U-shaped contactor with a single hollow fibre membrane under recirculation mode of operation
journal contribution
posted on 2012-11-07, 09:50 authored by Ksenija R. Kumric, Goran T. Vladisavljevic, Tatjana M. Trtic-PetrovicExtraction of Lu(III) from an aqueous LuCl3 solution at pH 3.5 into an organic phase containing 5%
(v/v) di(2-ethylhexyl)phosphoric acid (DEHPA) in di-n-hexyl ether (DHE) immobilized within a polypropylene hollow fibre membrane and a simultaneous back-extraction of Lu(III) into 2 mol dm-3
HCl solution has been investigated using two miniaturized supported liquid membrane (SLM) systems:
(i) a single hollow fibre membrane, with stagnant acceptor phase in the lumen, immersed into a donor
phase reservoir; (ii) U-shaped module containing a single hollow fibre membrane with a closed-loop
recirculation of aqueous phases through the module. In the stagnant SLM system, the maximum
extraction efficiency was 8.8% due to limited acceptor volume and absence of flow within the lumen. In
recirculating SLM system, after 80 min of operation at the donor phase flow rate of 5.3 cm3 min-1, the
acceptor phase flow rate of 0.4 cm3 min-1 and the donor-to-acceptor phase volume ratio of 6.7, the
equilibrium removal efficiency of Lu(III) reached 88% and less than 5% of Lu(III) extracted from the
feed solution was kept in the organic phase. For shell side flow of the donor phase at the Reynolds number of 3−34, the overall mass transfer coefficient was proportional to the donor flow rate raised to
the power of 0.63 and increased from 2.3 to 8.8 × 10-5 m s-1. The rate-limiting step was the mass transfer
of Lu(III) within the boundary layer of the donor phase adjacent to the outer wall of the hollow fibre.
History
School
- Aeronautical, Automotive, Chemical and Materials Engineering
Department
- Chemical Engineering
Citation
KUMRIC, K.R., VLADISAVLJEVIC, G.T. and TRTIC-PETROVIC, T.M., 2012. Membrane-assisted liquid phase extraction of Lu(III) in U-shaped contactor with a single hollow fibre membrane under recirculation mode of operation. Industrial and Engineering Chemistry Research, 51 (43), pp. 14199 - 14208.Publisher
© American Chemical SocietyVersion
- AM (Accepted Manuscript)
Publication date
2012Notes
This document is the Accepted Manuscript version of a Published Work that appeared in final form in Industrial and Engineering Chemistry Research [© American Chemical Society] after peer review and technical editing by the publisher. To access the final edited and published work see: http://dx.doi.org/10.1021/ie301887hISSN
0888-5885Publisher version
Language
- en