File(s) under permanent embargo
Reason: This item is currently closed access.
Synthesis and electrochemical properties of the naturally occurring free radical scavenger carazostatin
journal contribution
posted on 2013-01-17, 14:43 authored by P. Mark Jackson, Christopher J. Moody, Roger J. MortimerA short synthesis of the naturally occurring free radical scavenger carazostatin 1 starting from indol-3-ylacetic acid is described, the key step being the regiospecific Diels–Alder reaction of the indolopyrone 2 with ethyl trimethylsilylpropynoate. Electrochemical studies on carazostatin and some of its derivatives show it to be more easily oxidised than butylated hydroxytoluene (BHT).
History
School
- Science
Department
- Chemistry
Citation
JACKSON, P.M., MOODY, C.J. and MORTIMER, R.J., 1991. Synthesis and electrochemical properties of the naturally occurring free radical scavenger carazostatin. Journal of the Chemical Society, Perkin Transactions 1, 12, pp. 2941 - 2944.Publisher
© The Royal Society of ChemistryVersion
- VoR (Version of Record)
Publication date
1991Notes
This article is closed access, it was published in the serial Journal of the Chemical Society, Perkin Transactions 1 [© The Royal Society of Chemistry]. The definitive version is available at: http://dx.doi.org/10.1039/p19910002941ISSN
0300-922XPublisher version
Language
- en