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A rare and exclusive endoperoxide photoproduct derived from a thiacalix[4]arene crown-shaped derivative bearing a 9,10-substituted anthracene moiety
journal contribution
posted on 2016-05-16, 11:55 authored by Jiang-Lin Zhao, Chong Wu, Hirotsugu Tomiyasu, Xi Zeng, Mark ElsegoodMark Elsegood, Carl Redshaw, Takehiko YamatoA rare and exclusive endoperoxide photoproduct was quantitatively obtained from a thiacalix[4]arene crown-shaped derivative upon irradiation at λ=365 nm; the structure was unambiguously confirmed by ¹H/¹³C NMR spectroscopy and X-ray crystallography. The prerequisites for the formation of the endoperoxide photoproduct have also been discussed. Furthermore, the photochemical reaction rate could be greatly enhanced in the presence of the thiacalix[4]arene platform because it served as a host to capture oxygen.
Funding
We would like to thank the OTEC at Saga University and the International Cooperation Projects of Guizhou Province (No. 20137005) for financial support. The EPSRC is thanked for a travel grant (to CR).
History
School
- Science
Department
- Chemistry
Published in
Chemistry - An Asian JournalPages
n/a - n/aCitation
ZHAO, J. ... et al., 2016. A rare and exclusive endoperoxide photoproduct derived from a thiacalix[4]arene crown-shaped derivative bearing a 9,10-substituted anthracene moiety. Chemistry: an Asian Journal, DOI: 10.1002/asia.201600202.Publisher
© John Wiley & SonsVersion
- AM (Accepted Manuscript)
Publisher statement
This work is made available according to the conditions of the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0) licence. Full details of this licence are available at: https://creativecommons.org/licenses/by-nc-nd/4.0/Publication date
2016ISSN
1861-4728eISSN
1861-471XPublisher version
Language
- en