Thesis-1987-Hollinshead.pdf (13.52 MB)
Hydrogen evolution in KF–2HF
thesis
posted on 2018-05-17, 15:14 authored by Katharine HollinsheadThis thesis describes an electrochemical investigation of the
processes occurring at the hydrogen evolving cathode during the
industrial production of fluorine in molten KF–2HF. A 1A laboratory
cell, designed for the purposes of the project, is described.
Observations of the operation of this cell are reported. A comparison
of a range of electrode materials is given, both with regard to
electrochemical overvoltage and the bubbling releasing characteristics,
for which photographic evidence is presented. In addition,
measurements of the ohmic potential drop, caused by the presence of
bubbles, were made for different bubble types. Included in the above
is a description of any effects of metallic impurities present in the
melt both on overvoltage and bubble release. A mechanistic study of
hydrogen evolution on platinum is described and compared with the
reaction at a mild steel electrode. A preliminary investigation into
the use of parallel strand expanded metal electrodes was made and
further photographic evidence presented.
Funding
British Nuclear Fuels plc.
History
School
- Science
Department
- Chemistry
Publisher
© Katharine HollinsheadPublisher statement
This work is made available according to the conditions of the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0) licence. Full details of this licence are available at: https://creativecommons.org/licenses/by-nc-nd/4.0/Publication date
1987Notes
A Doctoral Thesis. Submitted in partial fulfilment of the requirements for the award of Doctor of Philosophy at Loughborough University.Language
- en