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Novel mono- and di-ferrocenyl bipyridyl ligands: syntheses, electrochemistry, and electropolymerisation studies of their ruthenium(II) complexes
journal contribution
posted on 2013-01-17, 14:56 authored by Paul D. Beer, Oldrich Kocian, Roger J. MortimerThe syntheses and electrochemical properties of new mono- and di-ferrocenyl bipyridyl ligands containing trans conjugated olefinic linkages between the ferrocene redox centres and the 4,4′-substituted 2,2′-bipyridine (bipy) moieties are described. The corresponding ruthenium(II) complexes have been prepared and one complex, [RuL4(bipy)2][PF6]2[L4= 4,4′-bis(ferrocenylvinyl)-2,2′-bipyridine], undergoes electrochemical polymerisation to produce an electrochromic polymer film.
History
School
- Science
Department
- Chemistry
Citation
BEER, P.D., KOCIAN, O. and MORTIMER, R.J., 1990. Novel mono- and di-ferrocenyl bipyridyl ligands: syntheses, electrochemistry, and electropolymerisation studies of their ruthenium(II) complexes. Journal of the Chemical Society, Dalton Transactions, 11, pp. 3283 - 3288.Publisher
© The Royal Society of ChemistryVersion
- VoR (Version of Record)
Publication date
1990Notes
This article is closed access, it was published in the serial Journal of the Chemical Society, Dalton Transactions [© The Royal Society of Chemistry]. The definitive version is available at: http://dx.doi.org/10.1039/dt9900003283ISSN
0300-9246Publisher version
Language
- en