Thesis-1998-Ross.pdf (4.5 MB)
Lead, indium and tin complexes of Schiff bases derived from salicylaldehydes
thesis
posted on 2017-10-10, 09:22 authored by Andrew T. RossA number of lead(II) complexes prepared from the reactions of various
disalicylaldimines with lead(II) salts have been characterised spectroscopically, and in
two cases have been analysed by X-ray diffraction. The reaction of
N,N'-bis(salicylidene)ethane-1,2-diamine (H2salen) with Pb(ClO4)2·6H2O produced a
novel complex [Pb3(salen)2][ClO4]2 in which the ligand bonds to the lead in two
different modes. The interaction of N,N'-bis(3-methoxy-salicylidene)ethane-1,2-diamine with Pb(ClO4)2·6H2O yielded a mononuclear complex wherein the ligand
bonds to the lead(II) atoms only through its phenolic oxygens. [Continues.]
Funding
EPSRC.
History
School
- Science
Department
- Chemistry
Publisher
© Andrew RossPublisher statement
This work is made available according to the conditions of the Creative Commons Attribution-NonCommercial-NoDerivatives 2.5 Generic (CC BY-NC-ND 2.5) licence. Full details of this licence are available at: http://creativecommons.org/licenses/by-nc-nd/2.5/Publication date
1998Notes
A Doctoral Thesis. Submitted in partial fulfilment of the requirements for the award of Doctor of Philosophy at Loughborough University.Language
- en