Thesis-1993-Crosby.pdf (4.75 MB)
Preliminary studies of the reactions of alkenyl α-nitroalkyl free radicals
thesis
posted on 2017-10-17, 10:32 authored by David CrosbyThe mechanistic fate of alkenyl α-nitroalkyl free
radicals generated in the following reactions has been
studied: SRN1 reactions between α-bromonitro compounds and
nucleophiles, reductive reactions between α-substituted
nitro compounds and tri-n-butyltin(IV)hydride (Bu3SnH) or
1,4-dihydro-N-benzylnicotinamide (BNAH), oxidative
reactions between alkenyl nitronate anions and nucleophiles
and the photolytic rearrangement of α-iodonitro compounds
have all been studied. [Continues.]
Funding
S.E.R.C. (Research Assistantship).
History
School
- Science
Department
- Chemistry
Publisher
© David CrosbyPublisher statement
This work is made available according to the conditions of the Creative Commons Attribution-NonCommercial-NoDerivatives 2.5 Generic (CC BY-NC-ND 2.5) licence. Full details of this licence are available at: http://creativecommons.org/licenses/by-nc-nd/2.5/Publication date
1993Notes
A Doctoral Thesis. Submitted in partial fulfilment of the requirements for the award of Doctor of Philosophy at Loughborough University.Language
- en