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The first thiadiazolidine 1-oxide system for phosphine-free palladium-mediated catalysis
journal contribution
posted on 2009-10-28, 12:17 authored by Benjamin BuckleyBenjamin Buckley, Stephen P. NearyWe herein report a highly active catalyst system using for the first time a thiadiazolidine
1-oxide as a ligand for palladium in the Mizoroki–Heck reaction. Excellent yields of stilbenes
derived from aryl iodides and bromides have been achieved using as little as 0.00002 mol%
catalyst. The ligand/palladium system can be stored as a stock solution open to air at room
temperature with no observable loss of activity for a period of several weeks/months.
History
School
- Science
Department
- Chemistry
Citation
BUCKLEY, B.R. and NEARY, S.P., 2009. The first thiadiazolidine 1-oxide system for phosphine-free palladium-mediated catalysis. Advanced Synthesis & Catalysis, 351 (1), pp. 71-77.Publisher
© Wiley-VCH Verlag GmbH & Co. KGaA, WeinheimVersion
- NA (Not Applicable or Unknown)
Publication date
2009Notes
This article is closed access. It was published in the journal, Advanced Synthesis & Catalysis [© Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim] at: http://dx.doi.org/10.1002/adsc.200800522ISSN
1615-4150;1615-4169Language
- en