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Please use this identifier to cite or link to this item: https://dspace.lboro.ac.uk/2134/11417

Title: Simplest Prussian-blue deposition from ferric ferricyanide solution by a reducing Ag spot put onto an ITO substrate
Authors: Barton, Ray T.
Kellawi, Hassan
Marken, Frank
Mortimer, Roger J.
Rosseinsky, David R.
Keywords: Prussian blue
Thin films
Issue Date: 2012
Publisher: © Springer-Verlag
Citation: BARTON, R.T. ... et al., 2012. Simplest Prussian-blue deposition from ferric ferricyanide solution by a reducing Ag spot put onto an ITO substrate. Journal of Solid State Electrochemistry, 16 (12), pp. 3723 - 3724.
Abstract: Prussian-blue (PB) film for electro-chromism can be electro-deposited on to an electrode (usually tin-doped indium oxide/glass) either directly from a PB colloid or from ferric ferricyanide in a two-electrode electro-chemical cell by applying a reductive potential. Alternatively, a “sacrificial” electron-producing silver flag electrode in the solution, when connected to the PB-receiving electrode, can effect the required reductive deposition. A silver spot, here innovatively applied as silver paint directly onto the deposition electrode, produces PB film on immersion in the iron(III)(III) solution, obviating the separate counter-electrode method.
Description: This article was published in the Journal of Solid State Electrochemistry [© Springer-Verlag] and the definitive version is available at: http://dx.doi.org/10.1007/s10008-012-1811-7
Version: Accepted for publication
DOI: 10.1007/s10008-012-1811-7
URI: https://dspace.lboro.ac.uk/2134/11417
Publisher Link: http://dx.doi.org/10.1007/s10008-012-1811-7
ISSN: 1432-8488
Appears in Collections:Published Articles (Chemistry)

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