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|Title: ||Simplest Prussian-blue deposition from ferric ferricyanide solution by a reducing Ag spot put onto an ITO substrate|
|Authors: ||Barton, Ray T.|
Mortimer, Roger J.
Rosseinsky, David R.
|Keywords: ||Prussian blue|
|Issue Date: ||2012|
|Publisher: ||© Springer-Verlag|
|Citation: ||BARTON, R.T. ... et al., 2012. Simplest Prussian-blue deposition from ferric ferricyanide solution by a reducing Ag spot put onto an ITO substrate. Journal of Solid State Electrochemistry, 16 (12), pp. 3723 - 3724.|
|Abstract: ||Prussian-blue (PB) film for electro-chromism can be electro-deposited on to an electrode (usually tin-doped indium oxide/glass) either directly from a PB colloid or from ferric ferricyanide in a two-electrode electro-chemical cell by applying a reductive potential. Alternatively, a “sacrificial” electron-producing silver flag electrode in the solution, when connected to the PB-receiving electrode, can effect the required reductive deposition. A silver spot, here innovatively applied as silver paint directly onto the deposition electrode, produces PB film on immersion in the iron(III)(III) solution, obviating the separate counter-electrode method.|
|Description: ||This article was published in the Journal of Solid State Electrochemistry [© Springer-Verlag] and the definitive version is available at: http://dx.doi.org/10.1007/s10008-012-1811-7|
|Version: ||Accepted for publication|
|Publisher Link: ||http://dx.doi.org/10.1007/s10008-012-1811-7|
|Appears in Collections:||Published Articles (Chemistry)|
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