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Title: Novel mono- and di-ferrocenyl bipyridyl ligands: syntheses, electrochemistry, and electropolymerisation studies of their ruthenium(II) complexes
Authors: Beer, Paul D.
Kocian, Oldrich
Mortimer, Roger J.
Issue Date: 1990
Publisher: © The Royal Society of Chemistry
Citation: BEER, P.D., KOCIAN, O. and MORTIMER, R.J., 1990. Novel mono- and di-ferrocenyl bipyridyl ligands: syntheses, electrochemistry, and electropolymerisation studies of their ruthenium(II) complexes. Journal of the Chemical Society, Dalton Transactions, 11, pp. 3283 - 3288.
Abstract: The syntheses and electrochemical properties of new mono- and di-ferrocenyl bipyridyl ligands containing trans conjugated olefinic linkages between the ferrocene redox centres and the 4,4′-substituted 2,2′-bipyridine (bipy) moieties are described. The corresponding ruthenium(II) complexes have been prepared and one complex, [RuL4(bipy)2][PF6]2[L4= 4,4′-bis(ferrocenylvinyl)-2,2′-bipyridine], undergoes electrochemical polymerisation to produce an electrochromic polymer film.
Description: This article is closed access, it was published in the serial Journal of the Chemical Society, Dalton Transactions [© The Royal Society of Chemistry]. The definitive version is available at: http://dx.doi.org/10.1039/dt9900003283
Version: Published
DOI: 10.1039/dt9900003283
URI: https://dspace.lboro.ac.uk/2134/11485
Publisher Link: http://dx.doi.org/10.1039/dt9900003283
ISSN: 0300-9246
Appears in Collections:Closed Access (Chemistry)

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