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Title: Highly stereoselective synthesis of z-homoallylic alcohols by kinetic resolution of racemic secondary allyl boronates
Authors: Incerti-Pradillos, Celia A.
Kabeshov, Mikhail A.
Malkov, Andrei V.
Issue Date: 2013
Publisher: © Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
Citation: INCERTI-PRADILLOS, C.A., KABESHOV, M.A. and MALKOV, A.V., 2013. Highly stereoselective synthesis of z-homoallylic alcohols by kinetic resolution of racemic secondary allyl boronates. Angewandte Chemie - International Edition, 52 (20), pp. 5338 - 5341
Abstract: α to Z: Racemic α-chiral allyl boronates, which are readily synthesized from the respective primary allyl halides, undergo a highly efficient kinetic resolution in a face- and Z-selective allylation of aldehydes catalyzed by the chiral Brønsted acid (R)-TRIP (see scheme; Epin=tetraethylethylene glycol). Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Description: This article is closed access, it was published in the journal Angewandte Chemie - International Edition [ © Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim]. The definitive version is available at: http://dx.doi.org/10.1002/anie.201300709
Sponsor: The authors thank the Leverhulme Trust for the Research grant F00 261AD and LU for a studentship to C.A.I.-P. We also thank Prof. T. Kanger (Tallinn University of Technology) for access to the computational resources as part of a collaboration within COST-ORCA action CM0905.
Version: Accepted for publication
DOI: 10.1002/anie.201300709
URI: https://dspace.lboro.ac.uk/2134/13543
Publisher Link: http://dx.doi.org/10.1002/anie.201300709
ISSN: 1433-7851
Appears in Collections:Closed Access (Chemistry)

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