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|Title: ||Highly stereoselective synthesis of z-homoallylic alcohols by kinetic resolution of racemic secondary allyl boronates|
|Authors: ||Incerti-Pradillos, Celia A.|
Kabeshov, Mikhail A.
Malkov, Andrei V.
|Issue Date: ||2013|
|Publisher: ||© Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim|
|Citation: ||INCERTI-PRADILLOS, C.A., KABESHOV, M.A. and MALKOV, A.V., 2013. Highly stereoselective synthesis of z-homoallylic alcohols by kinetic resolution of racemic secondary allyl boronates. Angewandte Chemie - International Edition, 52 (20), pp. 5338 - 5341|
|Abstract: ||α to Z: Racemic α-chiral allyl boronates, which are readily synthesized from the respective primary allyl halides, undergo a highly efficient kinetic resolution in a face- and Z-selective allylation of aldehydes catalyzed by the chiral Brønsted acid (R)-TRIP (see scheme; Epin=tetraethylethylene glycol). Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.|
|Description: ||This article is closed access, it was published in the journal Angewandte Chemie - International Edition [ © Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim]. The definitive version is available at: http://dx.doi.org/10.1002/anie.201300709|
|Sponsor: ||The authors thank the Leverhulme Trust for the Research grant F00 261AD and LU for a studentship to C.A.I.-P. We also thank Prof. T. Kanger (Tallinn University of Technology) for access to the computational resources as part of a collaboration within COST-ORCA action CM0905.|
|Version: ||Accepted for publication|
|Publisher Link: ||http://dx.doi.org/10.1002/anie.201300709|
|Appears in Collections:||Closed Access (Chemistry)|
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