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Title: An asymmetric synthesis of trans-fused butyrolactones from endoperoxides
Authors: Priest, Joshua
Longland, Mark R.
Elsegood, Mark R.J.
Kimber, Marc C.
Issue Date: 2013
Publisher: © American Chemical Society
Citation: PRIEST, J. ... et al, 2013. An asymmetric synthesis of trans-fused butyrolactones from endoperoxides. Journal of Organic Chemistry, 78 (7), pp. 3476 - 3481
Abstract: The intermolecular addition of 1,3-dicarbonyl equivalents to endoperoxides in the presence of an organocatalyst yields trans-fused butyrolactones in high yield and enantioselectivities. This methodology expands the synthetic utility of endoperoxides and further underlines their potential as sources of oxygen functionality for natural and non-natural product target synthesis.
Description: This article is closed access until April 2014, it was published in the serial Journal of Organic Chemistry [© American Chemical Society]. The definitive version is available at: http://dx.doi.org/10.1021/jo400177j
Version: Accepted for publication
DOI: 10.1021/jo400177j
URI: https://dspace.lboro.ac.uk/2134/13934
Publisher Link: http://dx.doi.org/10.1021/jo400177j
ISSN: 0022-3263
Appears in Collections:Published Articles (Chemistry)

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