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Please use this identifier to cite or link to this item: https://dspace.lboro.ac.uk/2134/13945

Title: Thiadiazolidine 1-oxide systems for phosphine-free palladium-mediated catalysis
Authors: Buckley, Benjamin R.
Neary, Stephen P.
Keywords: Catalysis
Phosphine-free
Heck
Thiadiazolidine
Palladium
Issue Date: 2010
Publisher: © Elsevier Ltd.
Citation: BUCKLEY, B.R. and NEARY, S.P., 2010. Thiadiazolidine 1-oxide systems for phosphine-free palladium-mediated catalysis. Tetrahedron, 66 (40), pp. 7988 - 7994.
Abstract: We herein report several highly active catalyst systems with thiadiazolidine 1-oxides as ligands for palladium in the Mizoroki–Heck reaction. Excellent yields of stilbenes derived from aryl iodides and bromides have been achieved using as little as 0.00002 mol % catalyst. The ligand/palladium system can be stored as a stock solution open to air at room temperature with no observable loss of activity for a period of several months.
Description: This article was published in the journal, Tetrahedron [© Elsevier Ltd.] and the definitive version is available at: http://dx.doi.org/10.1016/j.tet.2010.08.018
Version: Accepted for publication
DOI: 10.1016/j.tet.2010.08.018
URI: https://dspace.lboro.ac.uk/2134/13945
Publisher Link: http://dx.doi.org/10.1016/j.tet.2010.08.018
ISSN: 0040-4020
Appears in Collections:Published Articles (Chemistry)

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