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Title: The first enantiomerically pure thiadiazol-3-one 1-oxide and thiatriaza-indene 3-oxide systems chiral at the sulfur atom
Authors: Buckley, Benjamin R.
Neary, Stephen P.
Elsegood, Mark R.J.
Issue Date: 2010
Publisher: © Elsevier
Citation: BUCKLEY, B.R., NEARY, S.P. and ELSEGOOD, M.R.J., 2010. The first enantiomerically pure thiadiazol-3-one 1-oxide and thiatriaza-indene 3-oxide systems chiral at the sulfur atom. Tetrahedron: Asymmetry, 21 (16), pp. 1959 - 1962
Abstract: The first synthesis of an enantiomerically pure C2 symmetric benzothiadiazole 2-oxide is described along with the first synthesis of an enantiomerically thiadiazol-3-one 1-oxide and a thiatriaza-indene 3-oxide system both chiral at the sulfur atom. Excellent levels of diastereoselectivity were observed in the SO installation step, that is, the reaction of the prerequisite bis-amines with thionyl chloride at ambient temperature.
Description: This article was published in the journal Tetrahedron: Asymmetry [© Elsevier]. The definitive version is available at: http://dx.doi.org/10.1016/j.tetasy.2010.07.025
Version: Accepted for publication
DOI: 10.1016/j.tetasy.2010.07.025
URI: https://dspace.lboro.ac.uk/2134/13968
Publisher Link: http://dx.doi.org/10.1016/j.tetasy.2010.07.025
ISSN: 0957-4166
Appears in Collections:Published Articles (Chemistry)

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