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Please use this identifier to cite or link to this item: https://dspace.lboro.ac.uk/2134/15136

Title: The chemistry of new cyclic phosphorus(III) ligands
Authors: Ekubo, Allen T.
Issue Date: 2009
Publisher: © Allen Tobin Ekubo
Abstract: A range of new aniline derivatives of tetrakis(hydroxymethyl)phosphonium chloride represented as [P(CH2NHR)4]Cl, where R = phenyl or a substituted phenyl group were synthesised by reacting tetrakis(hydroxymethyl)phosphonium chloride with different aniline precursors in EtOH. Similarly, new phenylenediamine derivatives of tetrakis(hydroxymethyl)phosphonium chloride [P{(CH2NHhRh]Cl, [R = C614, C6H3Me, C6H3COPh, C6H2C414] were synthesised by reacting tetrakis(hydroxymethyl)phosphonium chloride with phenylenediamine precursors. Selected aniline derivatives of tetrakis(hydroxymethyl)phosphonium chloride were reacted with triethylamine in acetone at room temperature to give the corresponding diazaphosphorinane ligands cyclo- {CH2N(R)CH2N(R)CH2-P}-CH2N(H)R , where R = phenyl or a substituted phenyl group. Some of the diazaphosphorinane ligands were reacted with Ru(II), Rh(III), Ir(III) , Pd(lI) and Pt(lI) precursors to form new transition metal complexes... cont'd
Description: A Doctoral Thesis. Submitted in partial fulfillment of the requirements for the award of Doctor of Philosophy of Loughborough University.
URI: https://dspace.lboro.ac.uk/2134/15136
Appears in Collections:PhD Theses (Chemistry)

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