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Title: Double template effect in [4+4] Schiff base macrocycle formation; an ESI-MS study
Authors: Barreira-Fontecha, Julia
Kulmaczewski, Rafal
Ma, Xiaomei
McKee, Vickie
Issue Date: 2011
Publisher: © Royal Society of Chemistry
Citation: BARREIRA-FONTECHA, J. ... et al, 2011. Double template effect in [4+4] Schiff base macrocycle formation; an ESI-MS study. Dalton Transactions, 40(45), pp.12040-12043.
Abstract: The mechanism of self-assembly of a polynuclear complex of a [4 + 4] Schiff base iminomethylenediphenolate macrocycle [BaCu4(4 + 4)]2+ via a non-macrocyclic dialdehyde intermediate has been followed using ESI-MS of the reaction solutions. Both assembly of the intermediate and Schiffbase condensation with diamine give rise to single products; formation of the intermediate metallacycle is fast but Schiffbase condensation ismuch slower. Both intermediate complex andmacrocyclic product have been structurally characterised.
Description: This item is Closed Access.
Version: Closed access
DOI: 10.1039/c1dt11341k
URI: https://dspace.lboro.ac.uk/2134/15308
Publisher Link: http://dx.doi.org/10.1039/c1dt11341k
ISSN: 1477-9226
Appears in Collections:Closed Access (Chemistry)

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