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|Title: ||Studies on the double alkylation of 2,2-disubstituted-1,3-dithiacycloalkane-S-oxides: synthesis of tertiary thiol derivatives|
|Authors: ||Fuchs, Christian|
Elsegood, Mark R.J.
Weaver, George W.
|Issue Date: ||2013|
|Publisher: ||© Royal Society of Chemistry|
|Citation: ||FUCHS, C. ... et al., 2013. Studies on the double alkylation of 2,2-disubstituted-1,3-dithiacycloalkane-S-oxides: synthesis of tertiary thiol derivatives. RSC Advances, 3, pp.21911-21918.|
|Abstract: ||Di-alkylation of 2,2-dimethyl-1,3-dithiacycloalkane-S-oxides has been achieved allowing the synthesis of
two tertiary thiol centres. The diastereoisomers of the mono-alkylated products have been shown to
react at different rates. The X-ray crystal structures of three substituted dithiane-S-oxides have been
determined, and the conversion of the dialkylated products into cyclic disulfide derivatives of tertiary
thiols (1,2-dithiolanes) has been achieved by treatment with acid.|
|Sponsor: ||The authors thank Loughborough University for financial support.|
|Version: ||Accepted for publication|
|Publisher Link: ||http://dx.doi.org/10.1039/c3ra43688h|
|Appears in Collections:||Published Articles (Chemistry)|
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