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|Title: ||The first use of the free selenimide Ph(2)Se=NH as a synthon; the synthesis and X-ray crystal structure of [Ph(2)SeNSePh(2)][BPh(4)]|
|Authors: ||Elsegood, Mark R.J.|
Kelly, Paul F.
Staniland, Paul M.
|Issue Date: ||2008|
|Publisher: ||© The Royal Society of Chemistry|
|Citation: ||ELSEGOOD, M.R.J., KELLY, P.F., REID, G. ... et al., 2008. The first use of the free selenimide Ph(2)Se=NH as a synthon; the synthesis and X-ray crystal structure of [Ph(2)SeNSePh(2)][BPh(4)]. Dalton Transactions, 29, pp. 3798 - 3800.|
|Abstract: ||Reaction of o-mesitylsulfonylhydroxylamine (MSH) with Ph2Se results in the [Ph2SeNH2]+ cation; low temperature deprotonation (LDA), bromination (NBS) and then treatment with Ph2Se–Na[BPh4] generates [Ph2SeNSePh2][BPh4], via the selenimides Ph2Se[double bond, length as m-dash]NH and Ph2Se[double bond, length as m-dash]NBr.|
|Description: ||This article was published in the journal, Dalton Transactions [© Royal Society of Chemistry] and the definitive version is available at: http://dx.doi.org/10.1039/b806066e|
|Sponsor: ||EPSRC (EP/C510100) and the EPSRC
National Mass Spectrometry Service Centre at Swansea|
|Version: ||Accepted for publication|
|Publisher Link: ||http://dx.doi.org/10.1039/b806066e|
|Appears in Collections:||Published Articles (Chemistry)|
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