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Title: The first use of the free selenimide Ph(2)Se=NH as a synthon; the synthesis and X-ray crystal structure of [Ph(2)SeNSePh(2)][BPh(4)]
Authors: Elsegood, Mark R.J.
Kelly, Paul F.
Reid, Gillian
Staniland, Paul M.
Issue Date: 2008
Publisher: © The Royal Society of Chemistry
Citation: ELSEGOOD, M.R.J., KELLY, P.F., REID, G. ... et al., 2008. The first use of the free selenimide Ph(2)Se=NH as a synthon; the synthesis and X-ray crystal structure of [Ph(2)SeNSePh(2)][BPh(4)]. Dalton Transactions, 29, pp. 3798 - 3800.
Abstract: Reaction of o-mesitylsulfonylhydroxylamine (MSH) with Ph2Se results in the [Ph2SeNH2]+ cation; low temperature deprotonation (LDA), bromination (NBS) and then treatment with Ph2Se–Na[BPh4] generates [Ph2SeNSePh2][BPh4], via the selenimides Ph2Se[double bond, length as m-dash]NH and Ph2Se[double bond, length as m-dash]NBr.
Description: This article was published in the journal, Dalton Transactions [© Royal Society of Chemistry] and the definitive version is available at: http://dx.doi.org/10.1039/b806066e
Sponsor: EPSRC (EP/C510100) and the EPSRC National Mass Spectrometry Service Centre at Swansea
Version: Accepted for publication
DOI: 10.1039/b806066e
URI: https://dspace.lboro.ac.uk/2134/15622
Publisher Link: http://dx.doi.org/10.1039/b806066e
ISSN: 1477-9226
Appears in Collections:Published Articles (Chemistry)

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