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Title: Unusual metal-coordinated zwitterionic P-C-N-C-N-C phosphido adducts
Authors: Ekubo, Allen T.
Elsegood, Mark R.J.
Lake, Andrew J.
Smith, Martin B.
Issue Date: 2010
Publisher: © American Chemical Society
Citation: EKUBO, A.T. ... et al, 2010. Unusual metal-coordinated zwitterionic P-C-N-C-N-C phosphido adducts. Inorganic Chemistry, 49 (8), pp. 3703 - 3705.
Abstract: Rare examples of homodinuclear zwitterionic PdII and PtII complexes with bridging, two-coordinate P{cyclo-CH2N(R)CHN- (R)CH2} ligands (R = 4-FC6H4CH2, C6H5CH2) have been characterized by single-crystal X-ray diffraction using synchrotron radiation. Short N-C distances and enlarged N-C-N bond angles support electron delocalization in the central N-C-N backbone.
Description: This document is the unedited Author’s version of a Submitted Work that was subsequently accepted for publication in Inorganic Chemistry, copyright © American Chemical Society after peer review. To access the final edited and published work see: http://dx.doi.org/10.1021/ic1002308
Version: Submitted
DOI: 10.1021/ic1002308
URI: https://dspace.lboro.ac.uk/2134/15946
Publisher Link: http://dx.doi.org/10.1021/ic1002308
ISSN: 0020-1669
Appears in Collections:Published Articles (Chemistry)

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