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Title: | Isoxazole to oxazole: a mild and unexpected transformation |
Authors: | Jones, Raymond C.F. Chatterley, Alexander Marty, Romain Owton, W. Martin Elsegood, Mark R.J. |
Issue Date: | 2015 |
Publisher: | Royal Society of Chemistry |
Citation: | JONES, R.C.F. ... et al., 2015. Isoxazole to oxazole: a mild and unexpected transformation. Chemical Communications, 51 (6), pp. 1112 - 1115. |
Abstract: | 3-Aryltetrahydrobenzisoxazoles prepared en route to the coleophomone natural products and analogues, were found to undergo a remarkable base-mediated rearrangement to 2-aryltetrahydrobenzoxazoles. The scope of this unprecedented, facile transformation was probed: a range of analogues was produced, a mechanism proposed, and an application demonstrated by synthesis of a known herbicidal compound. |
Description: | This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. |
Version: | Published |
DOI: | 10.1039/c4cc07999j |
URI: | https://dspace.lboro.ac.uk/2134/16836 |
Publisher Link: | http://dx.doi.org/10.1039/c4cc07999j |
ISSN: | 1359-7345 |
Appears in Collections: | Published Articles (Chemistry)
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