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Title: Synthesis and solid state structure of pyridyl diboroxines linked by a chiral spacer analogous to Troger's base
Authors: Elsegood, Mark R.J.
Kimber, Marc C.
Keywords: Boronic acid
Chiral cleft
Issue Date: 2015
Publisher: © Elsevier Ltd
Citation: ELSEGOOD, M.R.J. and KIMBER, M.C., 2015. Synthesis and solid state structure of pyridyl diboroxines linked by a chiral spacer analogous to Troger's base. Tetrahedron Letters, 56 (2), pp. 346 - 349
Abstract: Pyridyl-assisted templating of phenyl boronic acid has been utilised to link two remote boroxines via a chiral spacer. The chiral spacer is a carbocyclic analogue of Tröger's base and contains a unique chiral cavity, and the flanking boroxine units have been shown, by single crystal X-ray analysis, to extend the size and shape of this cavity.
Description: NOTICE: this is the author’s version of a work that was accepted for publication in Tetrahedron Letters. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Tetrahedron Letters, vol 56, issue 2, January 2015, DOI:10.1016/j.tetlet.2014.11.094
Version: Accepted for publication
DOI: 10.1016/j.tetlet.2014.11.094
URI: https://dspace.lboro.ac.uk/2134/16853
Publisher Link: http://dx.doi.org/10.1016/j.tetlet.2014.11.094
ISSN: 0040-4039
Appears in Collections:Published Articles (Chemistry)

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