+44 (0)1509 263171
Please use this identifier to cite or link to this item:
|Title: ||Atropo- and diastereoselective construction of tetracyclic biphenylazepinium salts derived from aminoalcohols: use as catalysts in enantioselective asymmetric epoxidation.|
|Authors: ||Page, Philip C. Bulman|
Pearce, Christopher A.
Buckley, Benjamin R.
Rassias, Gerasimos A.
Elsegood, Mark R.J.
|Issue Date: ||2015|
|Publisher: ||© American Chemical Society|
|Citation: ||PAGE, P.C.B. ... et al, 2015. Atropo- and diastereoselective construction of tetracyclic biphenylazepinium salts derived from aminoalcohols: use as catalysts in enantioselective asymmetric epoxidation. Journal of Organic Chemistry, 80 (16), pp. 8036-8045.|
|Abstract: ||A range of new biphenylazepinium salt organocatalysts effective for asymmetric epoxidation has been developed incorporating an additional substituted oxazolidine ring, and providing improved enantiocontrol in alkene epoxidation over the parent structure. Starting from enantiomerically pure aminoalcohols, tetracyclic iminium salts were obtained as single diastereoisomers through an atroposelective oxazolidine formation|
|Description: ||This document is the Accepted Manuscript version of a Published Work that appeared in final form in Journal of Organic Chemistry, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://dx.doi.org/10.1021/acs.joc.5b01157|
|Sponsor: ||This investigation has enjoyed the support of Loughborough
University, the EPSRC, the University of East Anglia, and the
ERDF (ISCE-Chem & INTERREG IVa programme 4061). We
are indebted to the Royal Society for an Industry Fellowship
(to PCBP) and the EPSRC national mass spectrometry service
at the University of Wales, Swansea.|
|Version: ||Accepted for publication|
|Publisher Link: ||http://dx.doi.org/10.1021/acs.joc.5b01157|
|Appears in Collections:||Published Articles (Chemistry)|
Files associated with this item:
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.