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|Title: ||From chemical gardens to chemobrionics|
|Authors: ||Barge, Laura M.|
Cardoso, Silvana S.S.
Cartwright, Julyan H.E.
Cooper, Geoffrey J.T.
De Wit, Anne
Doloboff, Ivria J.
Goldstein, Raymond E.
Jones, David E.H.
Mackay, Alan L.
Pagano, Jason J.
Russell, Michael J.
Ignacio Sainz-Diaz, C.
Stone, David A.
Thomas, Noreen L.
|Issue Date: ||2015|
|Publisher: ||© American Chemical Society|
|Citation: ||BARGE, L.M. ... et al, 2015. From chemical gardens to chemobrionics. Chemical Reviews, 115 (16), pp. 8652 - 8703.|
|Abstract: ||Chemical gardens are perhaps the best example in chemistry of a
self-organizing nonequilibrium process that creates complex
structures. Many different chemical systems and materials can
form these self-assembling structures, which span at least 8
orders of magnitude in size, from nanometers to meters. Key to
this marvel is the self-propagation under fluid advection of
reaction zones forming semipermeable precipitation membranes
that maintain steep concentration gradients, with osmosis and
buoyancy as the driving forces for fluid flow. Chemical gardens
have been studied from the alchemists onward, but now in the
21st century we are beginning to understand how they can lead
us to a new domain of self-organized structures of semipermeable
membranes and amorphous as well as polycrystalline solids
produced at the interface of chemistry, fluid dynamics, and
materials science. We propose to call this emerging field
|Description: ||This is an open access article published under an ACS AuthorChoice License, which permits copying and redistribution of the article or any adaptations for non-commercial purposes. Details of the licence are available here: http://pubs.acs.org/page/policy/authorchoice_termsofuse.html|
|Sponsor: ||We acknowledge the U.S. National Science
Foundation, Grants CHE-0608631 and DMR-1005861, the
Spanish Ministerio de Ciencia e Innovación Grant FIS2013-48444-C2-2-P, and the Andalusian PAIDI group Grant
RNM363. L.M.B., I.J.D., and M.J.R.’s research was carried out
at the Jet Propulsion Laboratory, California Institute of
Technology, under a contract with the National Aeronautics
and Space Administration with support by the NASA Astrobiology
Institute (Icy Worlds).|
|Publisher Link: ||http://dx.doi.org/10.1021/acs.chemrev.5b00014|
|Appears in Collections:||Published Articles (Materials)|
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