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Title: Boron doped TiO2 catalysts for photocatalytic ozonation of aqueous mixtures of common pesticides: Diuron, o-phenylphenol, MCPA and terbuthylazine
Authors: Quinones, D.H.
Rey, A.
Alvarez, Pedro M.
Beltran, F.J.
Li Puma, Gianluca
Keywords: Photocatalytic ozonation
Boron doped TiO2
Boron leaching
Solar light
Issue Date: 2015
Publisher: © Elsevier
Citation: QUINONES, D.H., ...et al., 2015. Boron doped TiO2 catalysts for photocatalytic ozonation of aqueous mixtures of common pesticides: Diuron, o-phenylphenol, MCPA and terbuthylazine. Applied Catalysis B-Environmental, 178, pp. 74-81.
Abstract: Photocatalysts were characterized by ICP-EOS, N2 adsorption-desorption, XRD, XPS, and DR-UV-Vis spectroscopy. Four recalcitrant herbicides and pesticides (diuron, o-phenylphenol, 2-methyl-4-chlorophenoxyacetic acid (MCPA) and terbuthylazine) were subjected to degradation by ozonation, photolytic ozonation, photocatalysis and photocatalytic ozonation using the prepared catalysts under simulated solar irradiation in a laboratory scale system. The boron that was not incorporated to the TiO2 interstitial positions was unstable and leached to the solution. The washed B-doped TiO2 catalysts, with 0.5-0.8 wt.% of interstitial boron were more active than bare TiO2 for the removal and mineralization of the target compounds. The combination of ozonation and photocatalysis led to faster mineralization rates and allowed the complete removal of the pesticides below the regulatory standards. The B-doped catalyst was stable and maintained 75% mineralization after 3 consecutive runs.
Description: This paper was accepted for publication in the journal Applied Catalysis B-Environmental and the definitive published version is available at http://dx.doi.org/10.1016/j.apcatb.2014.10.036
Sponsor: This work has been supported by the Spanish Ministeriode Economía y Competitividad (MINECO)and European FederFunds through the project CTQ2012-35789-C02-01.
Version: Accepted
DOI: 10.1016/j.apcatb.2014.10.036
URI: https://dspace.lboro.ac.uk/2134/19056
Publisher Link: http://dx.doi.org/10.1016/j.apcatb.2014.10.036
ISSN: 0926-3373
Appears in Collections:Published Articles (Chemical Engineering)

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