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Title: Regio-selective substitution at the 1,3- and 6,8-positions of pyrene for the construction of small dipolar molecules
Authors: Feng, Xing
Tomiyasu, Hirotsugu
Hu, Jian-Yong
Wei, Xian-Fu
Redshaw, Carl
Elsegood, Mark R.J.
Horsburgh, Lynne
Teat, Simon J.
Yamato, Takehiko
Issue Date: 2015
Publisher: © American Chemical Society
Citation: FENG, X. ... et al, 2015. Regio-selective substitution at the 1,3- and 6,8-positions of pyrene for the construction of small dipolar molecules. Journal of Organic Chemistry, 80 (21), pp. 10973–10978.
Abstract: This article presents a novel asymmetrical functionalization strategy for the construction of dipolar molecules via efficient regioselective functionalization along the Z-axis of pyrene at both the 1,3- and 6,8-positions. Three asymmetrically substituted 1,3-diphenyl-6,8-R-disubsituted pyrenes were fully characterized by X-ray crystallography, photophysical properties, electrochemistry, and density functional theory calculations.
Description: This document is the Accepted Manuscript version of a Published Work that appeared in final form in Journal of Organic Chemistry, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see: http://dx.doi.org/10.1021/acs.joc.5b02128
Sponsor: This work was performed under the Cooperative Research Program of “Network Joint Research Center for Materials and Devices (Institute for Materials Chemistry and Engineering, Kyushu University)”. We thank the EPSRC (travel grants to C.R.), The Royal Society of Chemistry, The Scientific Research Foundation for the Returned Overseas Chinese Scholars, the State Education Ministry, and The Scientific Research Common Program of Beijing Municipal Commission of Education (18190115/008) for financial support. The Advanced Light Source is supported by the Director, Office of Science, Office of Basic Energy Sciences, of the U.S. Department of Energy under Contract DE-AC02-05CH11231.
Version: Accepted for publication
DOI: 10.1021/acs.joc.5b02128
URI: https://dspace.lboro.ac.uk/2134/19340
Publisher Link: http://dx.doi.org/10.1021/acs.joc.5b02128
ISSN: 1520-6904
Appears in Collections:Published Articles (Chemistry)

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