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|Title: ||Chemical functionalization of graphene oxide for improving mechanical and thermal properties of polyurethane composites|
|Authors: ||Jing, Qifei|
Silberschmidt, Vadim V.
|Issue Date: ||2015|
|Publisher: ||© Elsevier|
|Citation: ||JING, Q. ... et al, 2015. Chemical functionalization of graphene oxide for improving mechanical and thermal properties of polyurethane composites. Materials and Design, 85 pp.808-814|
|Abstract: ||Graphene oxide (GO) was chemically functionalized to manufacture polyurethane (PU) composites with improved mechanical and thermal properties. In order to achieve a well exfoliated and stable GO suspension in organic solvent, 4, 4′- methylenebis(phenyl isocyanate) and polycaprolactone diol – two monomers used to synthesize polyurethane – were employed to functionalize GO sequentially. The obtained functionalized GO (FGO) could form homogeneous dispersions in DMF solvent and the PU matrix, as well as provide a good compatibility with the latter. The most efficient improvement in mechanical properties was achieved when 0.4 wt% FGO was added into the PU matrix, corresponding to increases in the tensile stress, elongation at break and toughness by 34.2%, 27.6% and 64.5%, respectively (compared with those of PU). Regarding the thermal stability, FGO/PU 1 wt% showed the largest enhancement, with T2% and T50% 16 °C and 21 °C higher than those for PU, respectively. A significant improvement in both mechanical properties and thermal stability of FGO/PU composites should be attributed to homogeneous dispersion of FGO in the PU matrix and strong interfacial interaction between them.|
|Version: ||Submitted for publication|
|Publisher Link: ||http://dx.doi.org/10.1016/j.matdes.2015.07.101|
|Appears in Collections:||Published Articles (Mechanical, Electrical and Manufacturing Engineering)|
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