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|Title: ||Photocatalytic discolouration of Reactive Black 5 by UV-A LEDs and solar radiation|
|Authors: ||Rodriguez-Chueca, Jorge|
Ferreira, Leonor C.
Fernandes, Jose R.
Tavares, Pedro B.
Lucas, Marco S.
Peres, Jose A.
|Keywords: ||RB5 dye|
|Issue Date: ||2015|
|Publisher: ||© Elsevier Ltd.|
|Citation: ||RODRIGUEZ-CHUECA, J. ... et al, 2015. Photocatalytic discolouration of Reactive Black 5 by UV-A LEDs and solar radiation. Journal of Environmental Chemical Engineering, 3 (4A), pp.2948–2956|
|Abstract: ||One of the most important disadvantages of photocatalytic treatments is the high cost associated with the use of UV lamps. In this work, the efficiency of two UV-A LEDs (ultraviolet-a light emitting diodes) photosystems as a low cost alternative to conventional UV lamps was tested. The efficiency of the two UV-A LEDs photosystems was compared to that of the most economical UV source—solar radiation. To this end, the oxidative discolouration of Reactive Black 5 (RB5) aqueous solutions was studied using photocatalysis with different concentrations of TiO2 (0.5–1 g/L) and H2O2 (1.76, 4.41, 8.82 and 17.64 mM), exposed to different radiation sources: UV-A LEDs and solar radiation. The use of H2O2 increased the discolouration rate of RB5; however, an excessive dosage reduced the yield of the treatment, and the best results were attained with a concentration of 8.82 mM of H2O2. Strong differences were observed between the use of UV-A LEDs (23 W/m2) and solar radiation. In both cases total discolouration was observed, but the discolouration rate was considerably higher with solar radiation. However, the use of a more powerful UV-A LED photo-system (85 W/m2) allowed the achievement of higher discolouration rates (k = 0.284 min−1) than those obtained with solar radiation (k = 0.189 min−1) using only 0.5 g/L of TiO2. Therefore, UV-A LED radiation is a serious alternative to conventional UV lamps, since they are ecofriendly, have a low operational cost and high energy efficiency.|
|Description: ||This paper is closed access.|
|Sponsor: ||The authors are grateful to Fundação para a Ciência e a Tecnologia (FCT) and FEDER for the financial support provided to CQVR through PEst-C/QUI/UI0616/2014.|
|Version: ||Closed access|
|Publisher Link: ||http://dx.doi.org/10.1016/j.jece.2015.10.019|
|Appears in Collections:||Closed Access (Chemical Engineering)|
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