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Please use this identifier to cite or link to this item: https://dspace.lboro.ac.uk/2134/21319

Title: Chiral counterion strategy in Cu-catalyzed asymmetric allylic oxidation of linear alkenes
Authors: Incerti-Pradillos, Celia A.
Hudson, Daniel
Malkov, Andrei V.
Keywords: Allylic oxidation
Allylic esters
Asymmetric catalysis
Chiral counterion
Chiral phosphates
Regioselectivity
Issue Date: 25-Jan-2015
Publisher: De Gruyter Open
Citation: INCERTI-PRADILLOS, C.A., HUDSON, D. and MALKOV, A.V., 2015. Chiral counterion strategy in Cu-catalyzed asymmetric allylic oxidation of linear alkenes. Asymmetric Catalysis, 2(1): pp. 45-50.
Abstract: Application of a chiral counter-ion strategy in the Kharasch-Sosnovsky reaction is reported. Copper(I) phosphates obtained from axially chiral, BINOL-derived phosphoric acids were investigated as catalysts in the enantioselective allylic oxidation of acyclic alkenes. Good yields and high regioselectivity towards branched allylic ester have been achieved. The chiral phosphates investigated exhibited modest enantioselectivities.
Description: This is an Open Access Article. It is published by De Guyter Open under the Creative Commons Attribution 3.0 Unported Licence (CC BY). Full details of this licence are available at: http://creativecommons.org/licenses/by/3.0/
Version: Published
DOI: 10.1515/asorg-2015-0005
URI: https://dspace.lboro.ac.uk/2134/21319
Publisher Link: http://dx.doi.org/10.1515/asorg-2015-0005
Appears in Collections:Published Articles (Chemistry)

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