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Title: Selective formation of trimethylene carbonate (TMC): atmospheric pressure carbon dioxide utilization
Authors: Buckley, Benjamin R.
Patel, Anish P.
Wijayantha, K.G.U.
Keywords: Carbon dioxide utilization
Copper
Electrochemistry
Synthetic methods
Small ring systems
Issue Date: 2015
Publisher: © Wiley-VCH
Citation: BUCKLEY, B., PATEL, A. and WIJAYANTHA, K., 2015. Selective formation of trimethylene carbonate (TMC): atmospheric pressure carbon dioxide utilization. European Journal of Organic Chemistry, DOI: 10.1002/ejoc.201403385.
Abstract: Carbon dioxide utilisation (CDU) is currently gaining increased interest due to the abundance of CO2 and its possible application as a C1 building block. We herein report the first example of atmospheric pressure carbon dioxide incorporation into oxetane to selectively form trimethylene carbonate (TMC), which is a significant challenge as TMC is thermodynamically less favoured than its corresponding co-polymer.
Sponsor: B.R.B. and K.G.U.W. would like to thank Research Councils UK for RCUK fellowships and Loughborough University for funding a PhD studentship to A.P.P.
Version: Accepted for publication
DOI: 10.1002/ejoc.201403385
URI: https://dspace.lboro.ac.uk/2134/21365
Publisher Link: http://dx.doi.org/10.1002/ejoc.201403385
ISSN: 1434-193X
Appears in Collections:Closed Access (Chemistry)

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