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Title: Effect of hybrid reinforcement based on precipitated silica and montmorillonite nanofillers on the mechanical properties of a silicone rubber
Authors: Nik Ismail, Nik I.
Ansarifar, A.
Song, Mo
Issue Date: 2014
Publisher: © 2013 Society of Plastics Engineers. Published by Wiley.
Citation: NIK ISMAIL, N.I., ANSARIFAR, A. and SONG, M., 2014. Effect of hybrid reinforcement based on precipitated silica and montmorillonite nanofillers on the mechanical properties of a silicone rubber. Polymer Engineering and Science, 54(8), pp. 1909-1921.
Abstract: Silicone rubber (SR) nanocomposites containing precipitated silica (PS), montmorillonite (MMT) and PS/MMT hybrid fillers were prepared through melt-mixing technique. In the SR/PS/MMT nanocomposite, the hybrid filler weight ratio was increased progressively from 0.4 to 1.7 while keeping the MMT weight constant. The viscosity, cure characteristics and mechanical properties of the nanocomposites were subsequently measured. The optimum cure time increased and the scorch time and rate of cure decreased. Furthermore, when the hybrid filler weight ratio was raised to its optimum, the tensile strength, Young’s modulus, modulus at 100% and 300% elongation (M100 and M300), elongation at break, stored energy density at break and hardness of the nanocomposite improved. The stress-strain properties of the nanocomposite with the hybrid filler improved at high deformation in comparison with those containing the PS and MMT fillers. The MMT filler exfoliated in the SR/MMT nanocomposite but did not in the nanocomposites containing the hybrid filler. Notably, the mechanical properties of the nanocomposite benefitted from the hybrid filler. This was due to the filler-filler and filler-rubber network formation in the rubber by the PS particles. Finally, effect of the PS, MMT and hybrid fillers on the energy loss or hysteresis of the rubber was measured.
Description: This is the peer reviewed version of the following article: NIK ISMAIL, N.I., ANSARIFAR, A. and SONG, M., 2014. Effect of hybrid reinforcement based on precipitated silica and montmorillonite nanofillers on the mechanical properties of a silicone rubber. Polymer Engineering and Science, 54(8), pp. 1909-1921., which has been published in final form at http://dx.doi.org/10.1002/pen.23734. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving."
Version: Accepted for publication
DOI: 10.1002/pen.23734
URI: https://dspace.lboro.ac.uk/2134/21473
Publisher Link: http://dx.doi.org/10.1002/pen.23734
ISSN: 1548-2634
Appears in Collections:Published Articles (Materials)

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