Loughborough University
Leicestershire, UK
LE11 3TU
+44 (0)1509 263171
Loughborough University

Loughborough University Institutional Repository

Please use this identifier to cite or link to this item: https://dspace.lboro.ac.uk/2134/21641

Title: Controlling the assembly of C2-symmetric molecular tectons using a thiocarbamate appended carbocyclic cleft molecule analogous to Tröger’s base
Authors: Slater, Natasha H.
Buckley, Benjamin R.
Elsegood, Mark R.J.
Teat, Simon J.
Kimber, Marc C.
Issue Date: 2016
Publisher: © American Chemical Society
Citation: SLATER, N. ... et al., 2016. Controlling the assembly of C2-symmetric molecular tectons using a thiocarbamate appended carbocyclic cleft molecule analogous to Tröger’s base. Crystal Growth and Design, DOI: 10.1021/acs.cgd.6b00388.
Abstract: By way of appending the C2-symmetric carbocyclic cleft diol with thiocarbamates with varying substituents, significant control of the hydrogen bonded network can be achieved. Smaller alkyl substituents lead to the formation of stacked columns of components with the apex of one molecule suitably aligned in the cleft of a second. Aryl substituents however, lead to the formation of ribbons via an H-bonding network. Additionally, the packing of these ribbons into networks is considerably different between the enantiopure and racemic clefts, with the latter giving rise to channels within the crystal structure.
Description: Closed access until 18/05/2017.
Sponsor: We gratefully acknowledge financial support from Loughborough University (studentship for NHS). The Advanced Light Source is supported by the Director, Office of Science, Office of Basic Energy Sciences, of the U.S. Department of Energy under Contract No. DE-AC02-05CH11231.
Version: Accepted for publication
DOI: 10.1021/acs.cgd.6b00388
URI: https://dspace.lboro.ac.uk/2134/21641
Publisher Link: http://dx.doi.org/10.1021/acs.cgd.6b00388
ISSN: 1528-7483
Appears in Collections:Closed Access (Chemistry)

Files associated with this item:

File Description SizeFormat
Tecton submission revised.pdfAccepted version1.46 MBAdobe PDFView/Open

 

SFX Query

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.