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Title: Solution processing of CuIn(S,Se)2 and Cu(In,Ga)(S,Se)2 thin film solar cells using metal chalcogenide precursors
Authors: Arnou, Panagiota
Cooper, Carl S.
Ulicna, Sona
Abbas, Ali
Eeles, A.
Wright, Lewis D.
Malkov, Andrei V.
Walls, Michael
Bowers, Jake W.
Keywords: Chalcopyrite
Gallium content
Thin-film solar cells
Solution processing
Issue Date: 2016
Publisher: © The Authors. Published by Elsevier B.V
Citation: ARNOU, P. ... et al., 2016. Solution processing of CuIn(S,Se)2 and Cu(In,Ga)(S,Se)2 thin film solar cells using metal chalcogenide precursors. Thin Solid Films, in press, corrected proof, http://dx.doi.org/10.1016/j.tsf.2016.10.011
Abstract: In order to realize the true low cost potential of Cu(In,Ga)(S,Se)2 (CIGS) thin film solar cells, high performance needs to be combined with simple and easily controllable atmospheric-based deposition processes. A molecular solution-based approach for CIGS deposition is proposed, using metal chalcogenide precursors dissolved in an amine-thiol solvent combination. CIGS thin films were sprayed with varying Ga content and the sprayed films were incorporated into solar cells. The effect of the Ga content on the material and device properties is investigated. A champion power conversion efficiency of 9.8% (active area) was achieved, which highlights the potential of this methodology.
Description: This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/).
Sponsor: The authors would like to acknowledge EPSRC Supergen SuperSolar Hub for funding to support this project (EP/N508457/1, EP/J017361/1). The top contact grids and AR coating were deposited at Nanoco Technologies plc (UK).
Version: Published
DOI: 10.1016/j.tsf.2016.10.011
URI: https://dspace.lboro.ac.uk/2134/22825
Publisher Link: http://dx.doi.org/10.1016/j.tsf.2016.10.011
ISSN: 0040-6090
Appears in Collections:Published Articles (Chemistry)

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