Thesis-2017-Lilliman.pdf (9.73 MB)
Control of mortar rheology for 3D concrete printing
thesis
posted on 2021-12-02, 11:25 authored by Mary LillimanAdditive manufacturing is an emerging technology that is being used in
construction to remove the need for moulds and formwork. The 3D concrete
printing technique developed at Loughborough University involves the extrusion of
cement-based mortar, thus having broad similarities with the fused deposition
modelling type of additive manufacturing, but on a larger scale. The firstgeneration gantry beam was successful in printing flat and curved layers but was
relatively slow. In order to maintain sufficient open time for printing, a retarding
admixture was added to the mortar mix along with a superplasticizer to ensure that
the mix was the correct workability. More recently a second-generation printer has
been developed which utilises a robotic arm instead of a gantry. The speed of the
process has increased considerably but the process still has challenges in terms
of control. The rheological properties of the mortar affect its printability, in
particular the number of layers that can be placed at a time, and the quality and
strength of the final printed object. The rheology of cementitious systems, and
mortar especially, are not well described by existing theory, and this work aims to
add to the understanding of mortar rheology.
This research investigates the effect of the mortar rheology on the printing
process, which can be broken up into 3 areas: comparison of three techniques for
measuring the rheology, measurement of the deformation during printing, and
synthesis and characterisation of a superplasticizer. Due to the nature of this work
it therefore embodies both engineering and chemistry research, in an effort to
explore the structure property relationship between the mortar, its rheology and
the polycarboxylate based superplasticizer.
The three techniques for measuring the fluid properties of the printing mortar were
a building materials rheometer, a modified version of the geotechnical shear vane
and the slump flow test (BS EN 12350-8:2010). The yield stress and plastic
viscosity were calculated from the rheometer data, along with the viscosity index,
a measure of the Newtonian nature of the mortar. The plastic viscosity decreased
as superplasticizer concentration increased, but a poor trend was seen for yield
stress, although the yield stress for mixes containing the lowest superplasticizer concentration was significantly higher than for the other mixes. It was found that
above a superplasticizer concentration of 1.25% the viscosity index was close to
zero, suggesting that a yield stress does not exist. The shear vane test was used
as it is a relatively cheap, easy to carry out test but only gives a single value; the
vane shear strength, commonly correlated to the yield stress. Comparisons
showed though that the vane shear strength was related to both yield stress and
plastic viscosity. Videos were taken of the slump flow test to provide a more
dynamic measurement; as again the slump flow is usually a single point test.
Curve fitting was then undertaken to monitor the growth of the slump flow area
with time, and it was found that the slump flow values were linked to both plastic
viscosity and yield stress.
Mortars with three different superplasticizer concentrations were then printed to
observe the effect of rheology on the printability and in particular the height and
width of extrusions and the number of layers that could be built on top of each
other. The sizes of the voids in the printed samples were also determined by
image analysis. It was found that the mortar mixes containing the highest levels of
superplasticizer deformed more from the expected size. The mix containing 0.75%
superplasticizer had the least deformation, but had a high proportion of large voids
in the hardened samples. This mix had a significantly larger yield stress that the
others, suggesting that the yield stress is critical for void sizes. When deciding on
the appropriate rheological properties for use in printing there will be a balancing
act between expected shape and strength of hardened object.
A known polymer superplasticizer was then synthesised and the rheological
properties of mortar containing the superplasticizer measured. As the polymer
contained none of the additives associated with commercial superplasticizers the
direct effect of the polymer could be analysed. The polymer structure was
investigated by gel permeation chromatography, showing that specific synthesis
conditions were required. The polymers were then added to mortar and the
rheological properties assessed before deformation samples were produced. The
polymer had to be added to the mortar mix at a higher concentration than the
commercial superplasticizer used for the rest of the project. The reasons for this
were investigated further through the use of tuneable resistive pulse sensing
(TRPS) to measure the zeta potential of silica fume and superplasticizers.
Funding
Loughborough University, Graduate School.
History
School
- Architecture, Building and Civil Engineering
Publisher
Loughborough UniversityRights holder
© Mary LillimanPublisher statement
This work is made available according to the conditions of the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0) licence. Full details of this licence are available at: https://creativecommons.org/licenses/by-nc-nd/4.0/Publication date
2017Notes
A Doctoral Thesis. Submitted in partial fulfilment of the requirements for the award of Doctor of Philosophy of Loughborough University.Language
- en
Qualification name
- PhD
Qualification level
- Doctoral