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Title: Preliminary studies of the reactions of alkenyl α-nitroalkyl free radicals
Authors: Crosby, David
Issue Date: 1993
Publisher: © David Crosby
Abstract: The mechanistic fate of alkenyl α-nitroalkyl free radicals generated in the following reactions has been studied: SRN1 reactions between α-bromonitro compounds and nucleophiles, reductive reactions between α-substituted nitro compounds and tri-n-butyltin(IV)hydride (Bu3SnH) or 1,4-dihydro-N-benzylnicotinamide (BNAH), oxidative reactions between alkenyl nitronate anions and nucleophiles and the photolytic rearrangement of α-iodonitro compounds have all been studied. [Continues.]
Description: A Doctoral Thesis. Submitted in partial fulfilment of the requirements for the award of Doctor of Philosophy at Loughborough University.
Sponsor: S.E.R.C. (Research Assistantship).
URI: https://dspace.lboro.ac.uk/2134/26974
Appears in Collections:PhD Theses (Chemistry)

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