Thesis-1988-Bale.pdf (2.57 MB)
Retention-modification in HPLC using metal ions
thesis
posted on 2017-11-24, 09:30 authored by Simon J. BaleThe effects of transition metal ions as components of the
mobile phase on the retentions in HPLC of 2-aminophenol and
selected α-diketones were studied on both ODS-silica and porous
polymer columns. The compounds were used as model compounds in
an investigation which set out to derive a detailed
understanding of the mechanisms Involved when metal ions are
used to selectively modify the retention of compounds capable
of interaction. This technique, which has parallels with
ion-pair chromatography, provides another method by which the
conditions of a separation may be altered and the selectivity
adjusted to give better resolution. [Continues.]
History
School
- Science
Department
- Chemistry
Publisher
© S.J. BalePublisher statement
This work is made available according to the conditions of the Creative Commons Attribution-NonCommercial-NoDerivatives 2.5 Generic (CC BY-NC-ND 2.5) licence. Full details of this licence are available at: http://creativecommons.org/licenses/by-nc-nd/2.5/Publication date
1988Notes
A Doctoral Thesis. Submitted in partial fulfilment of the requirements for the award of Doctor of Philosophy at Loughborough University.Language
- en