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Thesis-1983-Granmayeh.pdf (10.93 MB)

Second virial coefficients of unsymmetrical and polar fluids

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posted on 2017-12-12, 09:35 authored by Assadollah Granmayeh
The second virial coefficients of twenty-one polar and/or non-symmetrical molecules have been fitted to these equations: (i) B(T) = b0 – a1T (exp (a2/T) – 1); (ii) B(T) = b0 – a1T–1/2 exp (a2/T); (iii) B(T) = –b0 [a1T (exp (a2/T – exp (ε/kT) + aT (exp (ε/kT – 1) – 1]. The first two equations have a semi-theoretical basis in the quasi-chemical or association approach. The first equation is a temperature modified square-well potential while the third equation is a two-step temperature modified square-well potential. [Continues.]

History

School

  • Aeronautical, Automotive, Chemical and Materials Engineering

Department

  • Chemical Engineering

Publisher

© A. Granmayeh

Publisher statement

This work is made available according to the conditions of the Creative Commons Attribution-NonCommercial-NoDerivatives 2.5 Generic (CC BY-NC-ND 2.5) licence. Full details of this licence are available at: http://creativecommons.org/licenses/by-nc-nd/2.5/

Publication date

1983

Notes

A Master's Thesis. Submitted in partial fulfilment of the requirements for the award of Master of Philosophy at Loughborough University.

Language

  • en

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