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Title: Second virial coefficients of unsymmetrical and polar fluids
Authors: Granmayeh, Assadollah
Issue Date: 1983
Publisher: © A. Granmayeh
Abstract: The second virial coefficients of twenty-one polar and/or non-symmetrical molecules have been fitted to these equations: (i) B(T) = b0 – a1T (exp (a2/T) – 1); (ii) B(T) = b0 – a1T–1/2 exp (a2/T); (iii) B(T) = –b0 [a1T (exp (a2/T – exp (ε/kT) + aT (exp (ε/kT – 1) – 1]. The first two equations have a semi-theoretical basis in the quasi-chemical or association approach. The first equation is a temperature modified square-well potential while the third equation is a two-step temperature modified square-well potential. [Continues.]
Description: A Master's Thesis. Submitted in partial fulfilment of the requirements for the award of Master of Philosophy at Loughborough University.
URI: https://dspace.lboro.ac.uk/2134/27739
Appears in Collections:MPhil Theses (Chemical Engineering)

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