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Please use this identifier to cite or link to this item: https://dspace.lboro.ac.uk/2134/27934

Title: Organo-sulfur phosphorus chemistry
Authors: Foreman, Mark R. StJ.
Issue Date: 1998
Publisher: © Mark R. StJ. Foreman
Abstract: P-organo-substituted dithiadiphosphetane disulfides have been prepared by the reaction of ferrocene and arenes with P4S10. Reaction of these compounds and Lawesson's reagent with alkenes, 2,3-dimethylbutadiene and other compounds gave organo-sulfur phosphorus compounds including 1,2-thiaphosphetane-2-sulfides such as P-ferrocenyl 1,2,5,5,7,8-hexamethyltricyclo[3,2,5,2,0]-3-thia-4-phospho-oct-7-ene-4-sulfide and a thiaphosphorine sulfide (P-ferrocenyl 4,5-dimethyl-3H,6H-1,2-thiaphosphinine-2-sulfide). Treatment of P-ferrocenyl thiaphosphorine sulfide with BuLi followed by carbon containing electrophiles (such as benzyl bromide or 2,4-dinitrochlorobenzene) gave ring-opened products. In addition treatment of dithiadiphosphetane disulfides with organic carbonyl compounds, including ketones, gave thiocarbonyl compounds. Platinum complexes were formed from the dithiadiphosphetane disulfides. [Continues.]
Description: A Doctoral Thesis. Submitted in partial fulfilment of the requirements for the award of Doctor of Philosophy at Loughborough University.
URI: https://dspace.lboro.ac.uk/2134/27934
Appears in Collections:PhD Theses (Chemistry)

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