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Please use this identifier to cite or link to this item: https://dspace.lboro.ac.uk/2134/32183

Title: Studies of dithioimidodiphosphinates and related compounds
Authors: Keyte, Robin W.
Issue Date: 1996
Publisher: © R.W. Keyte
Abstract: The condensation reaction of iPr2PCl with hexamethyldisilazane, HN(SiMe3)2, followed by oxidation with sulfur yields iPr2P(S)NHP(S)iPr2. Single crystal X-ray diffraction studies indicate it adopts a unique cisoid conformation in a hydrogen bonded chain. iPr2P(S)NHP(S)iPr2 was reacted with carbonates of Zn, Cd and Ni, CoCl2, MCl2COD (M = Pd, Pt) and Pt(PMe3)2Cl2 yielding the complexes M[iPr2P(S)NP(S)iPr2]2 (M = Zn, Cd, Ni, Co, Pd, Pt), {[iPr2P(S)NP(S)iPr2] Pd[iPr2P(S)NHP(S)iPr2]}+Cl- and {Pt(PMe3)2[iPr2P(S)NP(S)iPr2]}+BPh4-. [Continues].
Description: A Doctoral Thesis. Submitted in partial fulfilment of the requirements for the award of Doctor of Philosophy at Loughborough University.
Sponsor: EPSRC. Zeneca Specialties.
URI: https://dspace.lboro.ac.uk/2134/32183
Appears in Collections:PhD Theses (Chemistry)

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