Thesis-2006-Murphy.pdf (12.62 MB)
Electrochemistry of carbon nanofibre composite films
thesis
posted on 2018-06-29, 14:22 authored by Maria A. MurphyThe work carried out for this thesis focussed on four main areas: (i) the examination
and optimisation of the conditions for carbon nanofibre (CNF) growth, both
unsupported and as films on substrates; (ii) the electrochemical characterisation of the
CNF material before (as-grown) and after solubilisation (oxidation); (iii) the
formation and investigation of CNF thin film electrodes; and (iv) the (co-)deposition
of the CNFs with metals from aqueous plating solutions.
CNFs are grown at an iron nanoparticle catalyst produced from an iron oxide
precursor. After exploratory work with different types of iron oxide precursors, a
suitable and universally applicable catalyst is identified. CNFs are characterised by
electron microscopy, spectroscopy, and electrochemistry. When grown onto a ceramic
substrate, the 'as-grown' CNF material is shown to act as a porous, high surface area
electrode with the ability to strongly adsorb aromatic molecules, such as
hydroquinone, benzoquinone, and phenol. [Continues.]
Funding
Loughborough University, Faculty of Science. Dana Glacier Vandervell Bearings Ltd (Rugby).
History
School
- Science
Department
- Chemistry
Publisher
© M.A. MurphyPublisher statement
This work is made available according to the conditions of the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0) licence. Full details of this licence are available at: https://creativecommons.org/licenses/by-nc-nd/4.0/Publication date
2006Notes
A Doctoral Thesis. Submitted in partial fulfilment of the requirements for the award of Doctor of Philosophy at Loughborough University.Language
- en