Thesis-1968-Sinha.pdf (5.36 MB)
Co-ordination compounds of inorganic ambidentate ligands
thesis
posted on 2018-08-06, 14:11 authored by A.I.P. SinhaThe co-ordination compounds of inorganic ambidentate ligands
have been reviewed.
The preparation and properties of several cyanate complexes
of palladium(II) and platinum(II) of the types [M(NCO)4]2- and
[ML2(NCO)2] are described. A criterion for the diagnosis of the
mode of linkage of the cyanate group based upon the integrated
intensities of absorption of the C–N stretching bands has been
developed. The mode of linkage of the cyanate ion in these
complexes has been established from the positions of the infrared
bands and the intensities of absorption of the C–N stretching bands.
The effects of the ligands L on the bonding of the cyanate groups
have been discussed in the light of the spectral data. The coordination
behaviours of the NCX-(X = O, S or Se)-group of ligands
towards palladium(II) and platinum(II) have been compared and a
rationale for their differences has been proposed in terms of the
charge differences of the N and X atoms. In all these complexes,
the cyanate ion has been shown to be N-bonded. [Continues.]
Funding
Loughborough University of Technology, Department of Chemistry (research assistantship).
History
School
- Science
Department
- Chemistry
Publisher
© A.I.P. SinhaPublisher statement
This work is made available according to the conditions of the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0) licence. Full details of this licence are available at: https://creativecommons.org/licenses/by-nc-nd/4.0/Publication date
1968Notes
A Doctoral Thesis. Submitted in partial fulfilment of the requirements for the award of Doctor of Philosophy at Loughborough University.Language
- en