Thesis-2004-Fryatt.pdf (7.09 MB)
Heterobimetallic alkyne complexes and their use in asymmetric organic synthesis
thesis
posted on 2018-09-18, 11:04 authored by Ross FryattThis thesis describes the use of heterobimetallic alkyne complexes in asymmetric organic
synthetic pathways. Unlike previous protocols in the literature, the source of chiral
control is due to the inherent chirality of the heterobimetallic core and not from an
external source.
A new method for the preparation of Co(CO)3MoCp(CO)2-alkyne complexes has been
addressed with a view to a more rapid and cleaner preparation of these complexes,
adapting previously known literature methodology. Preparation of diastereomerically-enriched alcohol complexes has also been attempted. [Continues.]
Funding
EPSRC.
History
School
- Science
Department
- Chemistry
Publisher
© Ross FryattPublisher statement
This work is made available according to the conditions of the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0) licence. Full details of this licence are available at: https://creativecommons.org/licenses/by-nc-nd/4.0/Publication date
2004Notes
A Doctoral Thesis. Submitted in partial fulfilment of the requirements for the award of Doctor of Philosophy at Loughborough University.Language
- en