Thesis-1970-Goodacre.pdf (6.08 MB)
Crystal structures of some compounds containing phosphorus–sulphur bonds
thesis
posted on 2018-09-18, 11:57 authored by G.W. GoodacreThere is conflicting NMR and spectroscopic evidence in the
literature for the molecular structure of diphosphine disulphides.
Bis(cyclotetramethylene) diphosphine disulphide and bis(cyclopentamethylene)
diphosphine disulphide have been investigated by three-dimensional single
crystal X-ray techniques to determine their structure, to obtain accurate values for P–P and P→S bond lengths, and to observe any special
features resulting from the inclusion of phosphorus in heterocyclic rings.
A rough structure of tetramethyl diphosphine disulphide had previously
been published based on vary limited two-dimensional data, and this
structure has been confirmed and refined from three-dimensional data. [Continues.]
Funding
Science Research Council (research studentship and equipment grants).
History
School
- Science
Department
- Chemistry
Publisher
© G.W. GoodacrePublisher statement
This work is made available according to the conditions of the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0) licence. Full details of this licence are available at: https://creativecommons.org/licenses/by-nc-nd/4.0/Publication date
1970Notes
A Doctoral Thesis. Submitted in partial fulfilment of the requirements for the award of Doctor of Philosophy at Loughborough University.Language
- en