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Title: Bioinspired poly(vinylidene fluoride) membranes with directional release of therapeutic essential oils
Authors: Balzamo, G.
Willcock, Helen
Ali, Junaid
Ratcliffe, Elizabeth
Mele, Elisa
Issue Date: 2018
Publisher: © American Chemical Society
Citation: BALZAMO, G. ... et al, 2018. Bioinspired poly(vinylidene fluoride) membranes with directional release of therapeutic essential oils. Langmuir, 34 (29), pp.8652–8660.
Abstract: Here, the morphology of polypore fungi has inspired the fabrication of poly(vinylidene fluoride) (PVDF) membranes with dual porosity by nonsolvent-induced phase separation (NIPS). The fruiting body of such microorganisms is constituted of two distinct regions, finger- and sponge-like structures, which have been successfully mimicked by controlling the coagulation bath temperature during the NIPS process. The use of water at 10 °C as coagulant resulted in membranes with the highest finger-like/sponge-like ratio (53% of the total membrane thickness), while water at 90 °C allowed the formation of macrovoid-free membranes. The microchannels and the asymmetric porosity were used to enhance the oil sorption capacity of the PVDF membranes and to achieve directional release of therapeutic essential oils. These PVDF membranes with easily tuned asymmetric channel-like porosity and controlled pore size are ideal candidates for drug delivery applications.
Description: This document is the Accepted Manuscript version of a Published Work that appeared in final form in Langmuir copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.langmuir.8b01175
Version: Accepted for publication
DOI: 10.1021/acs.langmuir.8b01175
URI: https://dspace.lboro.ac.uk/2134/35232
Publisher Link: https://doi.org/10.1021/acs.langmuir.8b01175
ISSN: 0743-7463
Appears in Collections:Published Articles (Materials)

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