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Title: Synthesis of Tetracyclic 2,3-Dihydro-1,3-diazepines from a Dinitrodibenzothiophene derivative
Authors: Montanaro, Stephanie
Wright, Iain A.
Batsanov, Andrei S.
Bryce, Martin R.
Issue Date: 2018
Publisher: © American Chemical Society
Citation: MONTANARO, S. ... et al., 2018. Synthesis of Tetracyclic 2,3-Dihydro-1,3-diazepines from a Dinitrodibenzothiophene derivative. Journal of Organic Chemistry, 83(19), pp. 12320–12326.
Abstract: Triply fused 1,3-diazepine derivatives have been obtained by acidic reduction of rotationally locked and sterically hindered nitro groups in the presence of an aldehyde or ketone. The nitro groups are sited on adjacent rings of a dicyanodibenzothiophene-5,5-dioxide, which also displays fully reversible two-electron-accepting behavior. The synthesis, crystallographically determined molecular structures, and aspects of the electronic properties of these new molecules are presented.
Description: This paper is in closed access until 24th Sept 2019.
Sponsor: M.R.B. and I.A.W. thank EPRSC for funding (EP/K016164/1). I.A.W. thanks Loughborough University and the Royal Society of Chemistry Research Fund (RF18-5353) for funding.
Version: Accepted for publication
DOI: 10.1021/acs.joc.8b02029
URI: https://dspace.lboro.ac.uk/2134/35233
Publisher Link: https://doi.org/10.1021/acs.joc.8b02029
ISSN: 0022-3263
Appears in Collections:Closed Access (Chemistry)

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