Thesis-1976-Williams.pdf (3.6 MB)
The chemistry of dispirotetraenediones
thesis
posted on 2018-11-20, 12:30 authored by Ivor E. WilliamsA literature survey of the oxidative coupling of phenols and phenolic ethers has been carried out and is included. The thermal decomposition of dispiro-(5,0,5,3)-pentadeca-1,4,8,11-tetraene-3,10-dione, prepared by oxidation of the appropriate diphenol, has been studied in both solution and in the solid state. The decomposition in ethanol occurs by approximately first order kinetics at 74°C, the rate is not completely insensitive to concentration, however, suggesting a second order component. Decomposition in benzene is kinetically less regular: it is characterised by a slow initial phase followed by a more rapid reaction leading to complete decomposition. Addition of benzoyl peroxide has no effect on the decomposition rate in benzene; however, addition of 2,6-di-t-butyl-4-methyl phenol accelerates the decomposition in both benzene and ethanol. [Continues.]
Funding
Science Research Council (research studentship).
History
School
- Science
Department
- Chemistry
Publisher
© Ivor Edward WilliamsPublisher statement
This work is made available according to the conditions of the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0) licence. Full details of this licence are available at: https://creativecommons.org/licenses/by-nc-nd/4.0/Publication date
1976Notes
A Doctoral Thesis. Submitted in partial fulfilment of the requirements for the award of the degree of Doctor of Philosophy at Loughborough University.Language
- en