Thesis-1969-Vallance.pdf (22.99 MB)
The effect of para-substitution on properties of the N–H bond in anilines
thesis
posted on 2018-11-20, 17:16 authored by Victor VallanceThe effects of p-substitution on certain properties of the
N–H bond in aniline have been examined in this experimental
study.
The dipole moments and NH group stretching frequencies
of aniline, p-anisidine, p-toluidine, p-chloroaniline, p-bromoaniline
and p-cyanoaniline have been determined in
cyclohexane and dioxan and the affinity of these compounds
for dioxan in solution, and for an activated alumina adsorbent
at the solution–solid interface assessed.
Dipole moments have been calculated from measurements
of dielectric constant, refractive index and density of a
series of solutions of graded concentration. The affinity of
the anilines for dioxan have been determined from measurements
of optical density in the ultra-violet region of the spectrum. [Continues.]
History
School
- Science
Department
- Chemistry
Publisher
© Victor VallancePublisher statement
This work is made available according to the conditions of the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0) licence. Full details of this licence are available at: https://creativecommons.org/licenses/by-nc-nd/4.0/Publication date
1969Notes
A Doctoral Thesis. Submitted in partial fulfilment of the requirements for the award of the degree of Doctor of Philosophy at Loughborough University.Language
- en