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Title: Hybrid organic-inorganic rotaxanes, including a hetero-hybrid [3]rotaxane featuring two distinct heterometallic rings and a molecular shuttle
Authors: Timco, Grigore A.
Fernandez-Mato, Antonio
Kostopoulos, Andreas K.
Charlton, Jodie F.
Lockyer, Selena J.
Hailes, Thomas R.
Adams, Ralph W.
McInnes, Eric J.
Tuna, Floriana
Vitorica-Yrezabal, Inigo J.
Whitehead, George F.
Winpenny, Richard E.
Keywords: Heterospin
Quantum computing
Quantum information processing
Qubits
Rotaxanes
Issue Date: 2018
Publisher: © Wiley
Citation: TIMCO, G.A. ... et al, 2018. Hybrid organic-inorganic rotaxanes, including a hetero-hybrid [3]rotaxane featuring two distinct heterometallic rings and a molecular shuttle. Angewandte Chemie International Edition, 57 (34), pp.10919-10922.
Abstract: [2] and [3] hybrid rotaxanes are reported based on {Ti7M} rings (M is a trivalent metal such as FeIII or GaIII). NMR studies show that [2]rotaxanes can act as molecular shuttles, while EPR studies of [3]rotaxanes show weak interactions between the paramagnetic components of the supramolecular assemblies.
Description: This paper is closed access.
Sponsor: This work was supported by the University of Manchester, the EPSRC(UK, EP/L018470/1), and the EPSRC National EPR Facility. We also thank EPSRC(UK) for funding an X‐ray diffractometer (grant number EP/K039547/1).
Version: Published
DOI: 10.1002/anie.201805439
URI: https://dspace.lboro.ac.uk/2134/37375
Publisher Link: https://doi.org/10.1002/anie.201805439
ISSN: 1433-7851
Appears in Collections:Closed Access (Chemistry)

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