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Title: Crosslinking of rigid poly(vinyl chloride)
Authors: Gilbert, Marianne
Garcia-Quesada, J.C.
Issue Date: 1999
Publisher: © Maney Publishing
Citation: GILBERT, M. and GARCIA-QUESADA, J.C., 1999. Crosslinking of rigid poly(vinyl chloride). Plastics, Rubber and Composites, 28 (3), pp. 125 - 130
Abstract: Various formulations for the crosslinking of rigid poly(vinyl chloride) have been investigated including three different thermal stabilisers: a tin maleate; an octyl thio tin stabiliser; and a tribasic lead sulphate. The possibility of using aminosilanes and peroxides as crosslinking agents was considered and the additives used in the formulations were bis(-trimethoxysilylpropyl)amine, a blend of trimethylol propane trimethacrylate and amorphous silica, and 1,1-di-t-butylperoxy-3,3,5-trimethyl cyclohexane incorporating 40% peroxide. It was shown that rigid poly(vinyl chloride) can be crosslinked using both aminosilane and peroxide systems and the optimum level of the aminosilane was found to be 2 phr while significant property improvements were achieved with only 0·5 phr peroxide. The effects of the various thermal stabilisers and crosslinking additives are presented and discussed.
Description: This article was published in the journal, Plastics, Rubber and Composites [© Maney Publishing] and is available at: http://www.ingentaconnect.com/content/maney/prc
Version: Published
URI: https://dspace.lboro.ac.uk/2134/4502
ISSN: 1465-8011
Appears in Collections:Published Articles (Materials)

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