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Title: Spreading of trisiloxanes over thin aqueous layers
Authors: Lee, Khai S.
Starov, Victor
Muchatuta, T.J.P.
Srikantha, S.I.R.
Keywords: Trisiloxane
Surfactant solutions
Marangoni effect
Issue Date: 2009
Publisher: © Pleiades Publishing (distributed by Springer Science+Business Media LLC.)
Citation: LEE, K.S. ... et al, 2009. Spreading of trisiloxanes over thin aqueous layers. Colloid Journal, 71 (3), pp. 365–369
Abstract: Surfactants are widely spread in nature and are increasingly used in industry as wetting, cleaning and disinfecting agents. Recently, there are newly discovered trisiloxane and other silicone based surfactants which show very unusual spreading behaviour. Although a number of experimental and theoretical investigations have been carried out, the underlying spreading mechanism remains unclear. Experiments using trisiloxanes and comparison with 3 different ethylene glycol monododecyl ethers (C12E4, C12E5, and C12E6) surfactants were performed to understand the influence of Marangoni force as the driving force for the spreading. We then compared our experimental results to available theoretical prediction in the literature. The obtained experimental data showed the opposite trend as compared with the theoretical predictions developed for a regular surfactants. The latter is assumed to be a special feature of “suprspreaders”.
Description: This is a pre-publication version of the paper accepted for publication in the Colloid Journal [© Pleiades Publishing 2009]. The definitive version is available from: www.maik.ru or http://www.springer.com/chemistry/polymer/journal/10595
Version: Accepted for publication
DOI: 10.1134/S1061933X09030119
URI: https://dspace.lboro.ac.uk/2134/4911
Publisher Link: https://doi.org/10.1134/S1061933X09030119
ISBN: 1061-933X
ISSN: 1608-3067
Appears in Collections:Published Articles (Chemical Engineering)

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