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Title: The first thiadiazolidine 1-oxide system for phosphine-free palladium-mediated catalysis
Authors: Buckley, Benjamin R.
Neary, Stephen P.
Keywords: Mizoroki–Heck reaction
Thiadiazolidine
C–C coupling
Palladium
Catalysis
Issue Date: 2009
Publisher: © Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
Citation: BUCKLEY, B.R. and NEARY, S.P., 2009. The first thiadiazolidine 1-oxide system for phosphine-free palladium-mediated catalysis. Advanced Synthesis & Catalysis, 351 (1), pp. 71-77.
Abstract: We herein report a highly active catalyst system using for the first time a thiadiazolidine 1-oxide as a ligand for palladium in the Mizoroki–Heck reaction. Excellent yields of stilbenes derived from aryl iodides and bromides have been achieved using as little as 0.00002 mol% catalyst. The ligand/palladium system can be stored as a stock solution open to air at room temperature with no observable loss of activity for a period of several weeks/months.
Description: This article is closed access. It was published in the journal, Advanced Synthesis & Catalysis [© Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim] at: http://dx.doi.org/10.1002/adsc.200800522
Version: Closed access
DOI: 10.1002/adsc.200800522
URI: https://dspace.lboro.ac.uk/2134/5423
ISSN: 1615-4150
1615-4169
Appears in Collections:Closed Access (Chemistry)

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